with science and technology developing 、as science and techn

The second one is correct.
As science and technology develops,.
It is also correct to say:

With the development of science and technology,.


'with science and technology development' is Chinese English

'as developing science and technology' is wrong!

as..
is not so perfect

一般情况下用 (along) with science and technology developing

应该是：
with science and technology development
as developing science and technology
2者选其1